DILL, H.G. (2008) Diagenetic and epigenetic mineralisation in  Central Europe related to surfaces and depositional systems of sequence stratigraphic relevance.-

In:  J.M. Ketzer and S. Morad (eds.), Linking Diagenesis to Sequence Stratigraphy of Sedimentary Rocks, International Association of  Sedimentologists (IAS),

Special Publication,  Blackwell (accepted for publication).

 

Key:

 

1) Type of deposit

 

2. Age of mineralisation

 

3. Type localities

 

4. Element association

 

5. Mineral assemblage

 

6. Environment of deposition

 

7. Sequence stratigraphic control: SB = Sequence boundary, LST = Lowstand systems tract, TST = Transgressive systems tract, HST = Highstand systems tract, MFZ = Maximum flooding zone, TS = Transgressive surface

 

 

 

Near-shore oolitic marine ironstonesOrdovician (Llanvirn, Caradoc)-Schmiedefeld (Germany)- Gebersreuth (Germany)-Wittmannsgereuth (Germany)- Unterneuhüttendorf (Germany)-Ejpovice (Czech Republic)- Krušná Hora (Czech Republic) - Nučice(Czech Republic)- Zdice(Czech Republic)- Mníšek(Czech Republic)-Komárov (Czech Republic) - Fe-(P)- thuringite, chamosite, siderite, hematite, goethite, ± magnetite, ± pyrite, apatite, kaolinite (LOH) shelf sandstones/ shore face deposits (MOH) tempestites below the storm wave base (UOH) shore face, barrier and lagoon -(LOH) TS, (MOH) MFZ , (UOH) TS [LOH: Lower ore horizon, MOH: middle ore horizon. UOH: upper ore horizon]

 

Black-shale-hosted polymetallic pyrite deposits- Silurian and Early Devonian-Gera-Ronneburg (Germany)-Gräfenthal Horst (Germany)- Möschwitz (Germany)- Fe-Zn-Cu-Pb-U- (low metal concentrations of chalcophile elements and gold)- pyrite, marcasite, fahlore, sphalerite, galena, chalcopyrite, sooty pitchblende, apatite - euxinic deep marine shelf environments and marine slope environment-(TST ) MFZ

 

Carbonate-hosted  ironstones- Late Silurian (Ludlowian)- Gräfenthal Horst (Germany)- Fe- siderite (goethite)- swells topped by limestones undergoing karstification- HST with SB

 

Near-shore oolitic marine ironstones- Devonian- Walderbach (Germany)-Vervier (Belgium)-Dinant (Belgium)- Fe- Devonian- marine high energy regime (storm deposits)- MFZ (to lower HST)

 

Nearshore marine-paralic clayband- and blackband-type ironstones- Late Carboniferous- Ruhr District (Germany)-Saar-Nahe Basin (Germany) - Fe- siderite,  ± pyrite- paralic (floodplain, backswamps to nearshore intertidal marshes)- MFZ

 

Kaolin deposits- Carboniferous (Westphalian, Stephanian) Mesozoic, Cainozoic)- Karlovy Vary -Podbořany (Czech Republic)- Al-Si- kaolinite- chemical weathering caused by tropical to subtropical climates on a peneplain- SB

 

Unconformity-related uranium deposits- Permo-Mesozoic- Gera-Ronneburg (Germany)- U- pitchblende, chalcocite, bornite, sphalerite, chalcopyrite, As-Sb-Hg fahlore, galenite, pyrrhotite, niccolite, smythite, millerite, covellite, pyrite, bravoite, markasite, Ni-Co arsenide, hematite- chemical weathering caused by tropical to subtropical climates on a peneplain - SB

 

Sandstone-hosted kaolin deposits- Mesozoic- Hirschau-Schneidenbach (Germany)- Al-Si- kaolinite, plumbogummite- chemical weathering caused by tropical to subtropical climates on a peneplain and reworked into alluvial-fluvial deposits(HST)-SB

 

Vein-type F-Ba-U-bearing base metal deposits- Permian to Lower Jurassic- Dreislar (Germany), Wölsendorf-Nabburg (Germany), Käfersteige (Germany), Oberwolfach (Germany), Bad Grund (Germany), Maxonchamp (F), Val d´ Ajol (France), Münstertal (Germany), Freudenstadt (Germany), Eisenbach (Germany) F-Ba-Pb-Zn-U- fluorite, barite, galena, sphalerite, chalcopyrite, pyrite, marcasite, tetrahedrite, bournonite,  boulangerite, pyragyrite, pitchblende, ± coffinite- unconformity-related-(SB Þ LST-TS)

 

Sediment-hosted and vein-type base metal deposits- Post-Permian- Marsberg (Germany)- Cu-(Pb-Zn)- chalcopyrite, galena, sphalerite, selenides, native gold- unconformity-related- SB Þ TS-TST-MFZ

 

Sediment-hosted and vein-type F-Ba-bearing base metal deposits- Post-Permo-Triassic- Pingarten (Germany)- F-Ba-Pb- barite, fluorite, cerussite, quartz- alluvial-fluvial- SB Þ LST-TS

 

Sandstone-hosted base metal deposits- Jurassic- Maubach-Mechernich (Germany)- Pb-Zn- galena, sphalerite, chalcopyrite, bravoite, pyrite, tetrahedrite, bournonite, marcasite, covellite- alluvial-fluvial-lacustrine- SB Þ LST-TS

 

Coal- and  shale-bearing uranium deposits- Late Carboniferous to Early Permian- Intrasudetic basin (Poland), Kladno-Rakovnik (Czech Republic), Plzen basins (Czech Republic), Döhlen- (Freital) (Germany), Stockheim- (Germany), Weiden-( Germany), Oos-Saale-( Germany), Saar-Nahe basins (Germany), St. Hippolyte (France)- U-(Pb-Cu-Zn)- pitchblende, galena, sphalerite,  chalcopyrite, arsenopyrite, pyrite, marcasite- swamps and paludal – marginal lacustrine environments- MFZ

 

Sandstone-hosted  Cu-dominated base metal deposits - Middle to late Permian- Horní Vernéřovice (Czech Republic), Nowa Ruda (Poland), Okrzeszyn (Poland)- Cu-U-(Pb-Zn)- chalcocite, bornite, covellite, azurite and malachite, galena, sphalerite, sooty pitchblende- fluvial to lacustrine- MFZ to lower parasequences of the HST and upper parasequences of TST

MFZ Þ SB towards basin edge

 

Shale-hosted Cu-dominated base metal deposits (Kupferschiefer-type)- Late Permian –Triassic- Polkowice (Poland) –Konrad (Poland)-Lena (Poland)-Richelsdorf (Germany), Mansfeld-Sangerhausen (Germany), Spremberg-Weisswasser (Germany)-Cu-Pb-Zn (PGE)- chalcopyrite, bornite, chalcocite, tennantite, pyrite, galena, sphalerite, covellite, digenite, hematite, PGM- tide-dominated environment with flats and lagoons (sabkhas) under arid conditions- Upper parasequences of the TST grading through the MFZ into the lower parasequences of the HST

 

Sodium-, potassium and bitter salt-bearing evaporite deposits- Late Permian (Thuringian)-Zielitz (Germany)-Lehrte-Sehnde (Germany)- Borth (Germany)- Hengelo (The Netherlands)- Neuhof-Ellers (Germany) -Nowa Sól (Poland)- Eschwege (Germany)- Giershagen (Germany )- Na- K- Mg-(Br)-F-Sr- halite, sylvite, kieserite, carnallite, polyhalite, strontianite, celestite, fluorite- sabkhas- LST onlapping HST

 

Sandstone-hosted  Cu--dominated base metal deposits – Mesozoic- Twiste (Germany)- Wallerfangen (Germany)-Wrexen (Germany)-Helgoland (Germany)- Cu-U-(Pb-Zn-PGE-Ni-Se)- cuprite, malachite, chalcocite, digenite, anilite, bornite, stromeyerite, chalcopyrite, fahlore s.s.s., covellite, maucherite, niccolite,. pyrite, cattierite, berzelianite, naumannite, guanajuatite, uraninite, brannerite, gold, copper, PGE- fluvial to lacustrine- MFZ to lower parasequences of the HST and upper parasequences of TST

MFZ Þ SB towards basin edge

 

Carbonate-hosted Zn-dominated base-metal deposits- Triassic to Tertiary- Olkusz - Chrzanow /Upper Silesia (Poland)- Wieß­loch (Germany)- Zn-Pb- galena, sphalerite, pyrite, wurtzite, brunckite, marcasite, cerussite, smithsonite, goethite- barrier, lagoon, sabkha, near-shore marine brackish, karst- HST (SB)

 

Strontianite-, celestite- and fluorite deposits- Middle Triassic- Jena-Göschwitz (Germany)- F-Sr- strontianite, celestite, fluorite- sabkhas- HSTÞ SP  

 

Evaporite deposits- Middle Triassic- Bad Friedrichshall (Germany)- Heilbronn (Germany)- Haigerloch-Stetten (Germany)-Rheinfelden (Switzerland) - Zurzach (Switzerland)- Na- halite- sabkhas- LST

 

Sandstone-hosted Pb-dominated base metal deposits- Triassic with redeposition during the Cainozoic- Freihung (Germany)-Wollau (Germany) -Eichelberg (Germany)- Pb- cerussite, galena, ± chalco­pyri­te, ±sphalerite, ±bravoite, ±covellite, ±barite- fluvial-lacustrine/ playa-(TST)-HAST

 

Evaporite deposits- Late Triassic- Nancy (France)-Dieuze (France)- Na- halite- sabkhas- LST

 

Tabular sandstone-hosted uranium deposits- Late Triassic- Burgsandstein-Stubensandstein area (D)- U- sooty pitchblende, ± coffinite, apatite, ± tyuyamunite, ±carnotite- fluvial-swamp-playa- HST

 

Near-shore oolitic marine ironstones- Jurassic (Liassic to Malm)- Nancy (France), Landres-Ottange (France), Esch-Rumelange-Differdange (Luxembourg)- Gutmadingen (Germany)-Blumberg (Germany)-Geislingen (Germany)--Aalen (Germany)-Pegnitz (Germany)-Nammen (Germany)- Gifhorn (Germany)- Herznach (Switzerland)- Częstochowa – Zawiercie (Poland)-Lęczyca (Poland)- Fe-(P)- hematite, goethite, chamosite, siderite, leptochlorites, ± thuringite, ± magnetite, ± pyrite, apatite- near-shore marine high energy zone (regressional facies-(Fe) MFZ (P) TS Þ merging landward into SBs

 

Strontianite-, celestite- and fluorite deposits- Jurassic to Cretaceous- Deister Hills (Germany)-Hemmelte West (Germany)- Sr-Ca-S- celestite, anhydrite- sabkhas HSTÞ SP  

 

Near-shore marine pebble-ironstones- Cretaceous- Salzgitter (Germany)- Peine (Germany)- Fe- goethite-(fluvial)-marine (incised valley fill)- (SB) LST-TS

 

Near-shore marine pebble- and black-river ironstones- Late Cretaceous (Cenomanian)-Amberg-Sulzbach-Rosenberg (Germany)- Fe-P- goethite, siderite, apatite, ± REE-Fe-phosphate- fluvial-lacustrine-brackish (incised valley fill)- (SB) LST-TS

 

Unconformity-related sandstone-hosted uranium deposits- Post-Turonian -Königsstein (Germany) - Hamr (Czech Republic)- U- pitchblende- alluvial fan through near-shore marine siliciclastics- SB–LST-TST-MFZ

 

Kaolin-bauxite  deposits- Late Cretaceous and Tertiary- Tirschenreuth (Germany)- Goerlitz (Germany) - Meißen (Germany)- Czerwona Woda (Poland)- Zebrzydowa (Poland)- Strzegom (Poland) - Strzelin (Poland)-Znojmo (Czech Republic) - Weinzierl-Kriechbaum (A)-Bolesławice (Poland) –Westerwald (Germany)- Al-Si- kaolinite, ± gibbsite- chemical weathering caused by tropical to subtropical climates on a peneplain, in places reworked into deltaic deposits- SB Þ LST ?

 

Garnierite deposits- Cretaceous to Tertiary- Szklary (Poland)-Ząbkowice Sląskie (Poland)-St. Egidien (Germany)-Krěmže (Czech Republic) -  Tąpadła (Poland) - Góra Sleża (Poland)- Ni-(Mg)- garniertite, schuchartite, pimelite, amorphous magnesite- chemical weathering caused by tropical to subtropical climates on a peneplain- SB

 

Vein-type  base metal deposits- Cretaceous to Tertiary- Usingen (Germany)-Sauerland (Germany)- Brilon (Germany)-Ruhr District (Germany)- Si-Ca-Pb-Zn- quartz, calcite, galena, sphalerite- unconformity-related-(SB Þ LST-TS)

 

Carbonate-hosted base metal deposits- Jurassic-Lower Cretaceous (?)-

Aachen-Stollberg (Germany), Iserlohn-Schwelm (Germany) Brilon (Germany),  La Calamine (Belgium)- Pb-Zn-Ba- galena, sphalerite, barite, smithsonite, willemite, hemimorphite- unconformity-related/ karstification-(SB Þ LST-TS)

 

Sodium-, potassium and bitter salt-bearing evaporite deposits- Tertiary- Buggingen (Germany)- Na-K- halite, sylvite- sabkha- LST

 

Bauxite deposits- Miocene- Vogelsberg (Germany)- Al- gibbsite- unconformity-related- SB

 

Unconformity-related uranium deposits- late Miocene to early Pliocene- Rudolphstein (Germany) -Fuchsbau (Germany)- U- uranophane, torbernite, autunite- late Miocene to early Pliocene- unconformity-related- SB

 

Manganese–phosphate deposits- Neogene to Quaternary- Rheinisches Schiefergebirge (Germany) Franken-Thüringer Wald (Germany)  Schwarzwald (Germany)-Lahn area (D)- Fe-Mn-P- goethite, poorly-hydrated Mn oxides, manganomelane, Al-sulphate-phosphates- unconformity-related/ karstification- SB